Methods of preparing porous wood products for painting and finishing

ABSTRACT

Methods of preparing porous wood products for painting or finishing are described. The methods comprise applying to a porous wood product a UV-curable coating and curing by UV light the top UV curable coating to 70% to 95% cure, preferably 85% to 95% for spray-applied top UV curable coatings to produce a partially cured porous wood product. The methods typically further include the step of sanding the surface of the partially cured porous wood product and painting or staining, for example with a water-based or solvent-based stain or paint.

RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No.15/863,656, filed on Jan. 5, 2018 (published as US20180127613), which isa continuation-in-part application of U.S. application Ser. No.15/192,991 filed on Jun. 24, 2016 (now U.S. Pat. No. 10,017,661), whichclaims the benefit of U.S. Provisional Application No. 62/248,738 filedon Oct. 30, 2015 and U.S. Provisional Application No. 62/187,104 filedon Jun. 30, 2015, the contents of each of the which are incorporatedherein by reference thereto in their entireties.

TECHNICAL FIELD

This disclosure relates to methods and compositions of preparing porouswood products for painting and finishing, including methods forspray-applying compositions to porous wood products in preparation ofpainting and finishing to improve the quality of the finished product.

BACKGROUND

Painted wood products are in high demand in the market. Traditionalcabinet and furniture manufacturers include “painted” products in theiroffering. The cabinet industry, for example, offers about 40% of theentire offering in painted finishes. These painted finishes takemultiple steps to accomplish the final product and are typicallyproduced on hardwood veneer panels for every end panel and some interiorpanels as well. Hardwood veneers, however, are costly and also notsustainable.

On the other hand, the cost of porous panel products is drasticallylower than hardwood veneers. These products are also much moresustainable as they are by-products of the woodworking industryglobally. Porous panel products include medium-density fiberboard (MDF),high-density fiberboard (HDF), medium-density overlay (MDO), andhigh-density overlay (HDO). These boards are being used to replace muchmore expensive hardwood veneer panels and can provide a much higherfinishing capability than the hardwood veneer panels. The porous natureof these products, however, require proper sealing to increaseresistance to warping, expansion, shrinkage, or water damage.

Accordingly, there is a need for methods of sealing porous wood productsto achieve the same or better results in the final painting process thansealing hardwood while not increasing the finishing steps involved.These methods would also significantly reduce the end user's structuralcost. There is also need to provide a method of producing ahigh-quality, professional look similar to hardwood veneer panels orbetter. Finally, there is a need for methods that coat porous woodmaterials with various shapes that mimic the quality and look offinished hardwood.

BRIEF SUMMARY OF THE INVENTION

The present invention is directed to methods of preparing a porous woodproduct for painting or staining to improve the quality of a finishingcoat. The method typically includes applying to the porous wood producta top UV-curable coating. In certain embodiments the top UV-curablecoating includes at least one filler; partially cured to 70-95% cure,more preferably 80-95% cure or 85-95% cure; and sanded after partialcuring. When spray-applying the UV-curable coat partially curing the topUV-curable coating is preferable. A typical UV curing energy for the topUV-curable coating is 435-583 mJ/cm².

The methods of the invention generally include applying at least onenon-top UV-curable coating, e.g. 1, 2, or 3, and partially curing thenon-top UV-curable coating before, applying onto the partially curedporous wood product the top UV-curable coating. The disclosed methodsinclude compositions and procedures for spray-applying the UV-curablecoatings. In one exemplary embodiment, the porous wood product has oneor more side portions and the UV-curable coating is spray-applied to theone or more side portions. Preferably at least two UV-curable coatingsare spray-applied to the one or more side portions and the topUV-curable coating is partially cured to 85-95% cure. It is alsopreferable that the one or more side portions are sanded before applyinga UV-curable coating. In certain aspects of the disclosed method, atleast the partially cured top UV-curable coating is also sanded and morepreferably each partially cured UV-curable coating is sanded.

In one non-limiting embodiment, the method also includes applying awater-based tie coat to the porous wood product prior to applying aUV-curable coating.

The UV-curable coatings in certain embodiments are spray-applied.Typically there are between one and four UV-curable coatings, e.g., twoor three. Advantageously, each UV curable coating is preferably sandedafter partially curing, or at least the top UV curable coating is sandedbefore applying a finishing coat of paint or stain to the partiallycured top UV curable coating. In an exemplary embodiment, the porouswood product is sanded, with 180 grit sandpaper in preparation forapplying the first UV-curable coating. For the highest quality, eachUV-curable coating is sanded after partially curing, for example, using180 or 220 grit sandpaper, with the top UV-curable coating also beingsanded after partially curing, preferably with finer sand paper, forexample, using 320-400 grit sandpaper.

The top UV-curable coating is preferably applied with an applicationweight of 65-85 g/m² if one UV-curable coat is applied; 45-65 g/m² perlayer if two UV-curable coats are applied; and 35-55 g/m² per layer ifthree UV-curable coats are applied. In a non-limiting embodiment, atleast two UV-curable coatings are applied prior to spray-applying thetop UV-curable coating; and preferably all of the UV-curable coats arespray-applied. The combined application weight for all UV-curablecoatings is typically between 28-165 g/m² and 35-120 g/m².

The non-top UV-curable coatings are generally partially cured to 50-80%or 50-70% cure, and the top UV-curable coating is generally partiallycured to 70-95% and 85-95% if spray-applied. The UV-curable coatingtypically comprises at least one filler, for example, at 10-40% or20%-40% based on the total weight of the coating composition. Preferredfillers include: CaCO₃, silica, talc, silicone, Kaolin Clay, feldspar,titanium dioxide, and nepheline syenite. The UV-curable coating alsoincludes at least one monomer additive in certain embodiments,preferably selected from: DPGDA, HDODA, TRPDGA, TMPTA, TMPTMA, TPGDA,HDDA, and PETA.

The UV curable coating may further comprises a photoinitiator selectedfrom the group consisting of: 0.5-3%2-Hydroxy-2methyl-1-phenyl-1-propanone, 0.5-3%1-hydroxy-cyclohexyl-phenyl-ketone, and 0.5-3% Benzophenone; wherein the% of the photoinitiator is weight % based on the volume of the coatingcomposition.

A non-limiting specific example of a suitable UV-curable coatingcomposition, based on the total volume of the coating composition,includes: Amine Modified Polyether Acrylate at 25-45%; DipropyleneGlycol Diacrylate at 36-60%; Nepheline Syenite at 7-30%; Feldspar at6-30%; 2-Hydroxy-2methyl-1-phenyl-1-propanone: 0.5-3%;1-hydroxy-cyclohexyl-phenyl-ketone at 0.5-3%; and Benzophenone at0.5-3%.

BRIEF DESCRIPTION OF THE DRAWINGS

Implementations are described in conjunction with the appended drawings,where like designations denote like elements.

Skilled artisans will appreciate that elements in the figures areillustrated for simplicity and clarity and have not necessarily beendrawn to scale. For example, the dimensions of some of the elements inthe drawings may be exaggerated relative to others to help to improveunderstanding of implementations.

FIG. 1 depicts an example perspective view of a finished porous woodproduct.

FIGS. 2-4 depict cross-sectional views of porous wood products.

FIGS. 5 and 6 depict cross-sectional views of finished porous woodproducts.

FIGS. 7A-7C depict examples of various embodiments of preparing porouswood products.

FIG. 8 depicts an example process of preparing and finishing a porouswood product. Optional steps of the process are shown in boxes withdashed lines.

FIGS. 9-11 depict various embodiments of settings and targets for aprocess of preparing, and optionally finishing, porous wood products.

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT

The presently disclosed embodiments relate to the discovery thatapplying curable coatings to porous wood products and partially cure thetop UV-curable coating allow a variety of paints and finishes to adhereto the porous wood product.

Unless specifically noted, it is intended that the words and phrases inthe specification and the claims be given their plain, ordinary, andaccustomed meaning to those of ordinary skill in the applicable arts.The inventor is fully aware that he can be his own lexicographer ifdesired. The inventor expressly elects, as his own lexicographer, to useonly the plain and ordinary meaning of terms in the specification andclaims unless he clearly states otherwise and then further, expresslysets forth the “special” definition of that term and explains how itdiffers from the plain and ordinary meaning. Absent such clearstatements of intent to apply a “special” definition, it is theinventor's intent and desire that the simple, plain and ordinary meaningto the terms be applied to the interpretation of the specification andclaims.

The inventor is also aware of the normal precepts of English grammar.Thus, if a noun, term, or phrase is intended to be furthercharacterized, specified, or narrowed in some way, then such noun, term,or phrase will expressly include additional adjectives, descriptiveterms, or other modifiers in accordance with the normal precepts ofEnglish grammar. Absent the use of such adjectives, descriptive terms,or modifiers, it is the intent that such nouns, terms, or phrases begiven their plain and ordinary English meaning to those skilled in theapplicable arts.

The verb “comprise” as is used in this description and the claims andits conjugations are used in its non-limiting sense to mean that itemsfollowing the word are included, but items not specifically mentionedare not excluded. Also, reference to an element by the indefinitearticle “a” or “an” does not exclude the possibility that more than oneof the elements are present unless the context clearly requires thatthere is one and only one of the elements. The indefinite article “a” or“an” thus usually means “at least one.”

The term “porous wood product” refers to engineered wood products, whichare composite materials manufactured by binding or fixing the strands,particles, fibers, or boards of woods together with some method offixation. Specific examples of porous wood products include porous panelproducts such as medium-density fiberboard (MDF), high-densityfiberboard (HDF), medium-density overlay (MDO), high-density overlay(HDO), oriented strand board (OSB), particleboard, chipboard, panelproducts, and plywood. In preferred embodiments, “porous wood product”refers to a particleboard, chipboard, oriented strand board (OSB),medium-density fiberboard (MDF), high-density fiberboard (HDF),medium-density overlay (MDO), or high-density overlay (HDO).

The term “resin” refers to generally to synthetic materials that areviscous liquids capable of hardening permanently. Examples of resinsinclude polymers, oligomers, acrylics, acrylates, epoxies, urethanes,and polycarbonate.

The term “additive” refers to compounds that make the product flow,level, and/or defoam, for example, a deaerator. Accordingly, additivesinclude surface modifiers, curing agents, and the like.

The term “finishing coating” or “finishing coat” refers to coatinglayer(s) visible upon completion and final assembly of a product madefrom porous panel product, such as cabinetry, furniture, millwork, andfixtures. Generally, the finishing coating is applied to the partiallycured top UV-curable coat in the disclosed methods and consists ofpaint, stain, or both.

The terms “top UV-curable coating” or “top coating” refers to the lastUV-curable coating applied to the porous wood product.

The term “non-top UV-curable coating” refers to UV-curable coatinglayer(s) other than the top UV-curable coating layer.

The term “UV-curable coating” refers to the top and/or non-topUV-curable coating layer(s).

The term “partially cured” refers to curing to 97% cure or less, e.g.50% to 95%, 60% to 95%; 75% to 95%; 80% to 95%; 60% to 90%, 70% to 90%;85% to 95%, etc.

The present invention confers an advantage in improving thebrushability, chemical resistance, color uniformity, coverage,durability, flow, leveling, opacity, sheen uniformity, smoothness, andwater resistance of the finishing coating on a porous wood product.Compared to the prior art, preparing the porous wood product accordingto the disclosed methods results in improved coverage, better flow andenhanced durability of sealing coating, and reduced blemishes on thesurface. Furthermore, the surface of porous wood products may bemodified, for example, by etching or embossing, to give the appearanceof wood, hardwood veneers, non-wood patterns, etc.

The aspects, features, applications, and advantages will be apparent tothose of ordinary skill in the art from the specification, drawings, andthe claims. References are made to the figure to illustrate selectedembodiments and preferred modes of carrying out the invention. It is tobe understood that the invention is not hereby limited to those aspectsdepicted in the figure.

In general, the UV-curable coating formulations comprise at least 97%,at least 98%, at least 99%, or 100% solids and at least 50% resincontent. The spray coating formulations can be diluted with a reducingsolvent, e.g., N-Butyl Acetate to a preferred viscosity, measured in cP(centipoise) range from 60-125 cP. Unless otherwise noted,spray-application was accomplished using an HVLP (high volume, lowpressure) spray system. UV light is used at the specified dose topartially cure the coating. In typical embodiments, the solids are notreduced with a solvent as the preferred formulations have a low enoughviscosity to spray as formulated.

In one embodiment of the invention, a water-based tie coat is applied tothe porous wood product prior to applying UV-curable coatings to enhanceadherence of the UV-curable coatings.

Typically, the UV-curable coating formulations comprise no more than 50%of monomer additives. Preferred monomers include: DPGDA, HDODA, TRPDGA,TMPTA, TMPTMA, TPGDA, HDDA, and PETA. According to an aspect, theUV-curable coatings comprise a monomer additive selected from the groupconsisting of: TRPDGA, TMPTMA, and PETA. The amount of monomeradditive(s) may be 5-50% or any number range in between, e.g., 10-45%,15-40%, 20-50%, 35-45%, or 40-50%, by weight.

In general, the UV-curable coating formulations comprise a fillerselected from the group consisting of: CaCO₃, silica, talc, silicone,Kaolin clay, feldspar, titanium dioxide, and nepheline syenite. Theamount of filler(s) may be 5-50% or any number range in between, e.g.,5-20%, 5-40%, 10-25%, 10-45%, 10-50%, 15-35%, 15-45%, 20-40%, 25-45%,30-50%, 35-45%, 40-50%, by weight.

In general, the UV-curable coating formulations comprise aphotoinitiator selected from the group consisting of:2-Hydroxy-2methyl-1-phenyl-1-propanone,1-hydroxy-cyclohexyl-phenyl-ketone, and Benzophenone. The amount ofphotoinitiator(s) may be 0.1-3.5% or any number range in between, forexample, 0.1-1%, 0.1-1.5%, 0.1-2%, 0.1-2.5%, 0.1-3%, 0.1-3.5%, 0.5-1%,0.5-1.5%, 0.5-2%, 0.5-2.5%, 0.5-3%, 0.5-3.5%, 1-1.5%, 1-2%, 1-2.5%,1-3%, 1-3.5%, 1.5-2%, 1.5-2.5%, 1.5-3%, 1.5-3.5%, 2-2.5%, 2.5-3%, or2.5-3.5%.

In a non-limiting, preferred embodiment, UV-curable coating comprises,by volume:

30-50% acrylated epoxy; 10-20% Nepheline syneite; 10-20% Unsaturatedpolyester resin; 10-20% Trpdga;  1-10% 1,6-hexanediol diacrylate;  1-10%Magnesium silicate hydrate;  1-10% Acrylated amine;  1-10%1-hydroxycyclohecyl phenyl ketone;  1-10% Amorphous fumed silica;  1-10%Dipropyleneglycol diacrylate;  1-10% Benzophenone; <0.1% Ethylbenzene;<0.1% Toluene; <0.1% Naphthalene; and <0.1% Benzene.

In general, the spray-applicable UV-curable coating formulationscomprise:

-   -   a curable resin;    -   a reactive diluent;    -   a photoinitiator; and    -   a filler.

In a non-limiting, preferred embodiment, the spray-applicable UV-curablecoating formulations comprise, by volume:

25-45% Amine Modified Polyether Acrylate; 36-60% Dipropylene GlycolDiacrylate;  7-30% nepheline syenite;  6-30% Feldspar; 0.5-3%  2-Hydroxy-2methyl-1-phenyl-1-propanone; 0.5-3%  1-hydroxy-cyclohexyl-phenyl-ketone; and 0.5-3%   Benzophenone.

An aspect of the present invention provides applying a finishing coatingof water- or solvent-based paint or stain onto the sealed porous woodproduct. According to an aspect, the finishing coating further comprisesa coating, for example, a varnish or surface film, to seal the stain.According to a further aspect, the coating to seal the stain is a clearcoating.

The spray-applicable UV-curable coating formulation can be spray-appliedto any portion of the porous wood product. In one embodiment the porouswood product has one or more side portions and the UV-curable coating isspray-applied to at least the one or more side portions, for example,the UV-curable coating is spray-applied to the one or more side portionsand roller-applied to the top and bottom portions of the porous woodproduct. Preferably at least two UV-curable coatings are spray-appliedto the one or more side portions and the top UV-curable coating ispartially cured to 85-95% cure. In this embodiment, it is alsopreferable that the one or more side portions are sanded before applyinga UV-curable coating, followed by also sanding at least the partiallycured top UV-curable coating, but more preferably each partially curedUV-curable coating for the highest quality finish.

The top UV-curable coating is preferably applied with an applicationweight based on the number of UV-curable coatings applied. Non-limitingexamples include, one coat application at 65-85 g/m²; two-coatapplication at 45-65 g/m² per layer, and three-coat application at 35-55g/m² per layer.

In one embodiment, at least two UV-curable coatings are applied whenspray-applying the UV-curable coating, for example two to four layersare spray-applied. If the profile is more complicated, it is preferablethat additional UV-curable coatings are applied, e.g., three coatings intotal. In addition, before the initial UV-curable coating is applied, itis recommended that the product be sanded, for example, with 180 gritsandpaper. It is also recommended for the highest quality porous woodproducts that each non-top UV-curable coating be sanded after partialcuring, for example, using 180 or 220 grit sandpaper, with the topUV-curable coating also being sanded, preferably with finer sand paper,for example, using 320-400 grit sandpaper.

Depending on the number of UV-curable coatings to be applied to a porouswood product, the application weight consist of: 25-100 g/m², 30-95g/m², 35-85 g/m², 35-65 g/m², 45-85 g/m², 50-85 g/m², 55-80 g/m², 60-90g/m², 65-85 g/m², 25-65 g/m², 30-60 g/m², 30-55 g/m², 35-50 g/m². In anon-limiting, preferred embodiment, the top UV-curable coating may beapplied with an application weight selected from the group consistingof: 25-150 g/m², 25-120 g/m², 25-90 g/m², 28-120 g/m², 28-100 g/m²,28-80 g/m², 65-85 g/m²; 45-65 g/m², and 35-55 g/m² per layer.

The present invention provides methods for partially curing the topUV-curable coating, for example, partially curing to 45-97%, 50-97%,60-95%, 65-95%, 70-95%, 70-90%, 70-85%, 70-80%, 75-97%, 75-95%, 80-97%,80-95%, 85-90%, 85-95%, 85-97%, 90-95%, 90-97%, or 95-97%, including anyrange between 45% and 97% depending on the embodiment. In anon-limiting, preferred embodiment, the top UV-curable coating is curedto 85-95% cure.

The UV curing energy for curing the top UV-curable coating may be, forexample, 430-595 mJ/cm² and any specific range in between, e.g., 435-595mJ/cm², 440-585 mJ/cm², 450-475 mJ/cm², 460-540 mJ/cm², 465-565 mJ/cm²,470-580 mJ/cm², 480-590 mJ/cm², 490-570 mJ/cm², 500-510 mJ/cm², 500-570mJ/cm², 510-565 mJ/cm², 440-510 mJ/cm², 520-590 mJ/cm², 525-580 mJ/cm²,540-570 mJ/cm², 550-565 mJ/cm², 560-580 mJ/cm², or 590-595 mJ/cm². Innon-limiting, preferred embodiments, the UV curing energy for curing thetop UV-curable coating may be 435-525 mJ/cm², 435-583 mJ/cm², 435-495mJ/cm², 495-583 mJ/cm², or 495-525 mJ/cm². According to one exemplaryembodiment of the invention, the UV curing energy used to cure the topUV-curable coating is 435-583 mJ/cm².

According to an aspect of the present invention, prior to applying thetop UV-curable coating onto the porous wood product, a non-topUV-curable coating is applied. The non-top UV-curable coating ispreferably partially cured between 45-97% or any specific range inbetween, for example, 45-95%, 45-90%, 45-85%, 45-80%, 45-75%, 50-95%,55-75%, 55-90%, 60-95%, In a non-limiting, preferred embodiment, thenon-top UV-curable coating is cured to 50-70% cure.

The UV curing energy for curing the non-top UV-curable coating istypically, for example, 280-535 mJ/cm² or any specific range in between,e.g., 280-530 mJ/cm², 290-515 mJ/cm², 300-495 mJ/cm², 310-485 mJ/cm²,320-470 mJ/cm², 330-500 mJ/cm², 340-495 mJ/cm², 350-480 mJ/cm², 360-490mJ/cm², 370-515 mJ/cm², 385-465 mJ/cm², 395-515 mJ/cm², 410-510 mJ/cm²,425-480 mJ/cm², 435-530 mJ/cm², 455-485 mJ/cm², 485-525 mJ/cm², 525-535mJ/cm², and 530-535 mJ/cm². In a non-limiting, preferred embodiments,the UV curing energy for curing the non-top UV-curable coating is290-525 mJ/cm² or 290-495 mJ/cm².

An example of one aspect of the present invention is applying threeUV-curable coatings to the porous wood product. In a non-limitingexample, the first UV-curable coating is preferably cured to 50-95%,50-90%, or 50-75% cure with a UV curing energy of 290-583 mJ/cm²,290-525 mJ/cm², or 290-435 mJ/cm²; the second UV-curable coatingpreferably cured to 50-90%, 60-90%, or 60-75% cure with a UV curingenergy for curing the second UV-curable coating may be 350-525 mJ/cm² or350-435 mJ/cm², and the top UV-curable coating is preferably cured to70-97%, 75-95% or 80-95% with a curing energy of 435-583 mJ/cm².

An aspect of the invention provides sanding the porous wood productprior to the application of UV-curable coatings. A further aspect of thepresent invention provides sanding the surface of the partially curedtop UV-curable coat. In general, the sanding is done with sandpaper,sanding belt, or sanding disk. The sandpaper, sanding belt, or sandingdisk may have a grit selected from the group consisting of: 210 grit,220 grit, 230 grit, 240 grit, 250 grit, 260 grit, 270 grit, 280 grit,290 grit, 300 grit, 310 grit, 320 grit, 330 grit, 340 grit, 350 grit,360 grit, 370 grit, 380 grit, 390 grit, 400 grit, and 410 grit. Innon-limiting, preferred embodiments, the sandpaper, sanding belt, orsanding disk may have a grit selected from the group consisting of: 220grit, 320 grit, and 400 grit.

An aspect of the present invention provides modifying the surface of theporous wood product by etching or embossing. In general, etching may usesandpaper, sanding disc, sanding belt, or laser. In non-limiting,preferred embodiments, the sandpaper, sanding belt, or sanding disk hasa grit selected from the group consisting of: 24-80 grit, 24-60 grit,60-80 grit, 60 grit, and 80 grit.

An aspect of the present invention provides methods of preparing porouswood products for painting or staining, comprising: (a) applying onto aporous wood product a top UV-curable coating; (b) partially curing thetop UV-curable coating; and (c) sanding the partially cured top coat.

FIGS. 1-6 illustrate the methods for preparing porous wood productscomprising: (a) applying to a porous wood product (105) a UV-curablecoating, and (b) curing by UV light the UV-curable coating (115) to50-95% cure to produce a partially cured porous wood product (105). Insome implementations, the porous panel product 105 is selected from thegroup consisting of an MDF, an HDF, an MDO, and an HDO. In someimplementations, the UV curable coating 115 is cured to 50-75% cure,50-95% cure, and/or 60-95% cure.

Each of the at least one UV curable coatings 115 comprises, by volume,at least 97%, at least 98%, at least 99%, or 100% solids UV curablecoating and at least 50% resin content. The UV curable coating 115 mayalso comprise additives, which includes monomer additives and fillers.However, the percentage of additives in the UV curable coating 115 doesnot exceed 50% by volume. In preferred embodiments, the monomeradditives or the filler additives in the UV curable coating 115 each donot exceed 25% by volume. Examples of monomer additives in the UVcurable coating 115 include DiPropylene Glycol Diacrylate (DPGDA),6-hexanediol diacrylate (HDODA), tripropylene glycol diacrylat (TRPDGA),trimethylolpropane triacrylate (TMPTA), trimethylolpropanetrimethacrylate (TMPTMA), tripropylene glycol diacrylate (TPGDA),hexanediol diacrylate (HDDA) or pentaerythritol triacrylate (PETA).Examples of fillers in the UV curable coating 115 include CaCO₃, silica,talc, and silicone. A high amount of CaCO₃ or silicone (polymerizedsiloxanes) is not desirable in the UV curable coating 115. Preferably,the UV curable coating 115 comprises, by volume, less than 15%, lessthan 10%, less than 5%, preferably less than 1% CaCO₃. If the fillercomprises silicone, the silicone content is less than 1.5% by volume ofthe UV curable coating 115, though it is preferred that the UV curablecoating comprises no silicone. An exemplary UV curable coating 115 isthe HC UV Filler from RPM Wood Finishes Group, Inc. (Hickory, N.C.). Thecomposition of the HC UV Filler is depicted in Table 1.

TABLE 1 Composition and information on ingredients of HC UV Filler fromRPM Wood Finishes Group, Inc. Chemical Name % Composition (by volume)acrylated epoxy 30-50 nepheline syneite 10-20 unsaturated polyesterresin 10-20 TRPDGA 10-20 1,6-hexanediol diacrylate  1-10 magnesiumsilicate hydrate  1-10 acrylated amine  1-10 1-hydroxycyclohecyl phenylketone  1-10 amorphous fumed silica  1-10 dipropyleneglycol diacrylate 1-10 benzophenone  1-10 ethylbenzene <0.1 toluene <0.1 naphthalene <0.1benzene <0.1

FIGS. 2, 7A, and 9 illustrate an exemplary embodiment for preparing aporous wood product (particle, MDF, or HDF board 105) comprising:

(a) applying to the porous wood product a first UV-curable coating 110;

(b) curing by UV light the first UV-curable coating 110 to 50% to 70%cure;

(c) applying to the porous panel product a second UV-curable coating120;

(d) curing by UV light the second UV-curable coating 120 to 60% to 90%cure;

(e) applying to the porous panel product a third UV-curable coating 130;and

(f) curing by UV light the third UV-curable coating 130 to 85% to 95%cure to produce a porous wood product ready for painting or finishing.The first, second, and third UV-curable coatings (110, 120, and 130) maycomprise the same or different UV-curable coatings 115.

FIGS. 3, 7B, and 10 illustrate an exemplary embodiment for preparing aporous wood product (particle board 105) comprising:

(a) applying to the porous wood product a first UV-curable coating 110;

(b) curing by UV light the first UV-curable coating 110 to 50% to 70%cure;

(c) applying to the porous panel product a second/top UV-curable coating120; and

(d) curing by UV light the second UV-curable coating 120 to 75% to 85%cure to produce a porous wood product ready for painting or finishing.

The first and second UV-curable coatings (110 and 120) may comprise thesame or different UV-curable coatings 115.

FIGS. 4, 7C, and 10 illustrate an exemplary embodiment for preparing aporous wood product (MDF or HDF board 105) comprising:

(a) applying to the porous wood product a first/top UV-curable coating110; and

(b) curing by UV light the first UV-curable coating 110 to 85% to 90%cure to produce a porous wood product ready for painting or finishing.

FIG. 5 illustrates methods for finishing a porous wood product 105comprising

(a) applying to a porous panel product 105 at least one UV-curablecoating 115;

(b) curing by UV light the at least one UV-curable coating 115 to 50% to95% cure; and

(c) applying to the sealed porous wood product a finishing coating 190.The finishing coating 190 may be paint or some other finishing product.

FIG. 8 illustrates exemplary embodiments for preparing a porous woodproduct. In certain embodiments, the porous wood product is sanded priorto application of the UV curable coating (115) using sandpaper orsanding disk having 180 grit, 220 grit, or 320 grit. Sanding (810) priorto application of the UV curable coating is recommended if the surfaceof the porous panel product 105 is not sufficiently clean for adhesionof applied coatings.

Adhesion of the UV curable coating 115 to the porous panel product 105may also be increased by the application of water-based tie coat (820).Thus, in certain embodiments, the methods further comprise applying awater-based tie coat (820) to the porous wood product (105). Thus theapplication step would take place just before the application of thefirst layer of the UV-curable coating (110). The application of thewater-based tie coat (820) is recommended if the porous wood product(105) is poorly pressed.

Prior to finishing the sealed porous wood product (105) with paint orother finishing products (190), the methods may further comprisemodifying (860) the surface of the porous wood product (105), resultingin a varied surface (175). In some embodiments, the modification (860)enables the surface of the sealed porous panel product (105) to bestained. The modification (860) may merely be sanding the surface of thesealed porous wood product (105) to smooth the sealed surface forfinishing, for example, by using 220 grit, 320 grit, or 400 gritsandpaper or sand disk. Modifying (860) the surface of the sealed porouswood product may also introduce varied surface (175) as decorativepatterns for the porous wood product, for example, a finished appearancethat mimics wood grains 180, like the hardwood veneer (see FIGS. 1, 5,and 6). The wood grains (180) appearance may be etched or embossed ontothe surface of the porous wood product (105). The porous wood product(105) may be etched by laser or by chemicals. The wood grains (180)appearance may also be made on the surface of the porous wood product(105) by sandblasting.

In one embodiment, the surface of the sealed porous panel product 105may be etched with 24 grit to 80 grit sandpaper or sanding belt toproduce the decorative pattern (e.g., wood grains 180) that mimics thegrains of mahogany wood. In a preferred embodiment for generating theappearance wood grains 180, the sandpaper or sanding belt used formimicking actual wood grains is between 60 grit to 80 grit. The pressureof the sanding affects the final wood grain 180 appearance. Sandingdeeper into the sealed porous panel product 105 will result in a darkappearance. On the other hand, sanding lighter into the sealed porouspanel product 105 will produce lighter appearance and also lighterdefinition of the mimicked wood grains 180.

In other embodiments, an embosser may be used to modify the surface ofthe porous wood product (105) to give the appearance of wood grains(180) that has patterned grains, such as oak. In some embodiments, alaser may be used to etch the surface of the porous wood product (105)to give either the unpatterned wood grain (180) pattern like that ofmahogany or patterned wood grain (180) pattern like that of oak. In someimplementations, an actual image of a wood pattern (for example cherrywood or oak wood) may be the basis for embossing pattern. Thus theembossing cylinder of the embosser may be laser or router etched withthe actual image of the wood pattern to reproduce the actual image ontothe surface of the porous wood product (105) as wood grain (180). Inimplementations where the modification of the surface of the porous woodproduct (105) comprises embossing, sanding the surface of the porouswood product (105), for example, by using 220 grit, 320 grit, or 400grit sandpaper or sand disk may take place before or after theembossing.

Unlike porous wood products (105) that are not treated with thedisclosed preparation process, the porous wood product (105) may bestained with any wood strain. Thus either water-based or solvent-basedstain may be used on the porous wood product (105). Accordingly, oilstains, varnish stains, water-based stains, gel stains, lacquer stains,water-soluble dye stain, or metal-complex (metalized) dye stains may beused to stain the porous wood product. The porous wood product (105) maybe further finished (870) by the application of a varnish or surfacefilm that seals the stain. In some embodiments, the varnish or surfacefilm is a coating. In some embodiments, the varnish or surface film is afinish coating (190).

FIGS. 9-11 describe non-limiting examples of application weights, curingenergies, and curing amounts for the first UV-curable coating 110, theoptional second UV-curable coating 120, and the optional third UVcurable coating 130.

The present disclosure is further illustrated by the following examplesthat should not be construed as limiting. The contents of allreferences, patents, and published patent applications cited throughoutthis application, as well as the Figures, are incorporated herein byreference in their entirety for all purposes.

EXAMPLES Example 1. Comparison of Finished Products Treated or Untreatedwith the Disclosed Preparation Process

Porous wood products (105) were finished with one coat of a pigmentedconversion varnish was spray-applied at three wet mils without anysealing treatment or over a sealed surface. The sealed surface wasproduced by with application of three UV-curable coatings (115) appliedvia roll coaters. The first layer of a UV-curable coating (110) waspartially cured at 65% before the application of a second UV-curablecoating (120). The second layer of UV-curable coating (120) waspartially cured at 60% before the application of a third UV-curablecoating (130), which was partially cured at 80%. The coated surface wasthen sanded (860) with 320 grit sandpaper using a sanding machine.

The finished porous wood product (105) treated with preparation processof the disclosure has better color uniformity compared the finishedporous wood product (105) that did not receive the treatment. Thewhiteness and sheen are more evenly distributed on the porous woodproduct (105) treated with the preparation process of the disclosure.The treatment also provided a smoother finished surface. The finishedporous wood product (105) treated with the preparation process of thedisclosure also has greater chemical and water resistance propertiesthan the product that did not receive the treatment.

Example 2. Comparison of Finished Products Treated with Just a Primerand Treated with a Primer and the Disclosed Preparation Process

For a porous wood product (105) that was treated using just a primer,two coats of a pigmented primer were spray-applied at three wet mils perapplication to the untreated surface, then sanded with 400 gritsandpaper. The surface was finished with one coat of a pigmentedconversion varnish spray-applied at three wet mils. For the porous woodproduct (105) that was treated with the preparation process of thedisclosure, the sealed surface was produced by application of threeUV-curable coatings (115, e.g., 110, 120 and 130) applied via rollcoaters. The first layer of a UV-curable coating (110) was partiallycured at 65% before the application of a second UV-curable coating(120). The second layer of UV-curable coating (120) was partially curedat 60% before the application of a third UV-curable coating (130), whichwas partially cured at 80%. One coat of a pigmented primer wasspray-applied at three wet mils to the surface, then sanded (860) with400 grit sandpaper. Lastly, one coat of a pigmented conversion varnishwas spray-applied (870) at three wet mils to the surface to achieve thefinal finish coat (190).

A comparison between treated and untreated porous wood productsdemonstrates the superiority of the treated porous wood product (105)processed according to the disclosed methods compared to using multiplelayers of spray-applied primer. Multiple layers of spray-applied primerdo not provide the same finish properties as the treated porous woodproduct (105) processed according to the disclosed methods. The porouswood product (105) processed according to the disclosed methods hasincreased opacity, durability, a smoother appearance and feel, and used50% less spray-applied primer.

Example 3. Comparison of Finished MDF Treated with to the Methods of thePrior Art and Treated with the Preparation Process of the Disclosure

Methods for preparing MDFs in the prior art involve the application ofprimers, which is apparent as an additional layer on the fiberboard. Thedisclosed process, however, uses a UV curable coating (115) that doesnot add to the additional bulk while still smoothing the surface for theapplication of a finishing coating. In spite of primers essentiallyproviding an additional layer to the MDF that should provide a smoothersurface for the finishing coating, the surface produced by disclosedmethods provides a smoother and higher quality surface for the finishingcoating producing a MDF product that is similar in quality to real wood.This is made apparent by comparing the reflection of light on thefinished MDF treated with to the methods of the prior art and on thefinished MDF treated with the preparation process of the disclosure. Thereflection on the finished surface from an MDF treated with thepreparation process of the disclosure provides nearly a mirror-likereflection. On the other hand, the finished MDF that was primed (ratherthan prepared by the process of the disclosure) has a rough surface thatshows a heavily distorted reflection. Accordingly, preparing the porouswood product according to the methods of the disclosure improves theflow, leveling, sheen uniformity, and smoothness of the finishingcoating.

Example 4: The Finished Porous Wood Product Treated with the PreparationProcess of the Disclosure is Modified and Stained to Look Like Mahogany

The finished porous wood product (105) treated with the preparationprocess of the disclosure may be further finished with a stainingtreatment. The surface of a finished MDF was etched (860) usingsandpaper to introduce the appearance of mahogany grains prior to theapplication of the stain. The grains were introduced onto the surface ofthe MDF using sandpaper between 60 grit to 80 grit. Because the MDF wastreated with the disclosed preparation process and only partially curedprior to the application of the stain, the stain was able to absorb intothe porous wood product (105) completely and can show grain definition.The partially curing process of the disclosure allows the porous woodproduct (105) to have both a “hard” and “soft” surface that is verysimilar to a true hardwood like mahogany. These differences in hard andsoft allow the stain product to penetrate at different rates thus givinga “natural” appearance.

What is claimed is:
 1. A method of preparing a porous wood product forpainting or staining to improve chemical resistance and/or waterresistance properties of the porous wood product, the method comprising:a. applying to the porous wood product a coat of UV-curable coating; b.partially curing the UV-curable coating; c. applying onto the partiallycured porous wood product a top UV-curable coating; and d. partiallycuring the top UV-curable coating to 80-95% cure, wherein the topmostUV-curable coating is not fully cured; and the improved chemicalresistance and/or water resistance properties result in increasedresistance to warping, expansion, shrinkage, and/or water damage.
 2. Themethod of claim 1, wherein the porous wood product has one or more sideportions and wherein the UV-curable coating is spray-applied to the oneor more side portions.
 3. The method of claim 1, wherein at least twoUV-curable coatings are applied prior to applying the top UV-curablecoating and the combined application weight for all UV-curable coatingsis selected from the group consisting of: 28-100 g/m², 28-120 g/m²,45-120 g/m², and 45-180 g/m².
 4. The method of claim 1, furthercomprising applying a water-based tie coat to the porous wood productprior to applying a UV-curable coating, and wherein the UV-curablecoating is partially cured to 50-70% cure, and the top UV-curablecoating is cured to 85-95% cure.
 5. The method of claim 1, wherein theUV-curable coatings are spray-applied and comprise 10-40% filler basedon the total weight of the coating compositions, with the top UV-curablecoating cured to 85-95% cure.
 6. The method of claim 1, wherein theUV-curable coating comprises 20-40% filler based on the total weight ofthe coating composition.
 7. The method of claim 1, wherein the topUV-curable coatings comprises at least one filler selected from thegroup consisting of: CaCO3, silica, talc, silicone, Kaolin Clay,feldspar, titanium dioxide, and nepheline syenite.
 8. The method ofclaim 7, wherein the filler is feldspar.
 9. The method of claim 1,wherein the UV-curable coating comprises, based on the total volume ofthe coating composition: a. Amine Modified Polyether Acrylate: 25-45%;b. Dipropylene Glycol Diacrylate: 36-60%; c. nepheline syenite: 7-30%;d. Feldspar: 6-30%; e. 2-Hydroxy-2methyl-1-phenyl-1-propanone: 0.5-3%;f. 1-hydroxy-cyclohexyl-phenyl-ketone: 0.5-3%; and g. Benzophenone:0.5-3%.
 10. The method of claim 1, wherein a wood grains appearance isembossed onto the surface of the porous wood product or etched by laseror by chemicals onto the surface of the porous wood product.
 11. Amethod of preparing a porous wood product for painting or staining toimprove chemical resistance and/or water resistance properties of theporous wood product, the method comprising: a. applying to the porouswood product a top UV-curable coating, wherein the top UV-curablecoating comprises at least one filler; and b. partially curing the topUV-curable coating to 70-95% cure, wherein the topmost UV-curablecoating is not fully cured; and the improved chemical resistance and/orwater resistance properties result in increased resistance to warping,expansion, shrinkage, and/or water damage.
 12. The method of claim 11,wherein the top UV-curable coating is spray-applied and the filler isselected from the group consisting of: CaCO3, silica, talc, silicone,Kaolin Clay, feldspar, titanium dioxide, and nepheline syenite.
 13. Themethod of claim 12, wherein filler is feldspar.
 14. The method of claim11, wherein the top UV-curable coating is applied with an applicationweight of 65-85 g/m² if one UV-curable coat is applied; 45-65 g/m² perlayer if two UV-curable coats are applied; and 35-55 g/m² per layer ifthree UV-curable coats are applied.
 15. The method of claim 11, furthercomprising the step of spray-applying between two and four UV-curablecoatings, sanding each UV-curable coating after partially curing, andapplying a finishing coating of paint or stain to the sanded andpartially cured top UV-curable coating.
 16. The method of claim 11,wherein the UV-curable coating further comprises a photoinitiatorselected from the group consisting of: 0.5-3%2-Hydroxy-2methyl-1-phenyl-1-propanone, 0.5-3%1-hydroxy-cyclohexyl-phenyl-ketone, and 0.5-3% Benzophenone; wherein the% of the photoinitiator is weight % based on the total volume of thecoating composition.
 17. The method of claim 11, wherein the UV curingenergy of the top UV-curable coating is 435-583 mJ/cm².
 18. The methodof claim 11, wherein the top UV-curable coating comprises at least onemonomer additive selected from the group consisting of: DPGDA, HDODA,TRPDGA, TMPTA, TMPTMA, TPGDA, HDDA, and PETA.
 19. The method of claim11, wherein the UV-curable coating comprises 10-40% filler based on thetotal weight of the coating composition.
 20. The method of claim 11,wherein a wood grains appearance is embossed onto the surface of theporous wood product or etched by laser or by chemicals onto the surfaceof the porous wood product.